The four processes of silicification in continental settings are pedogenic, groundwater, hydrothermal and evaporite replacement. In order to understand the origin of the Brian Head silicified beds, petrographic and geochemical analyses were conducted.
The paragenetic sequence of mineral formation of the silicified layers is: 1) precipitation of micrite, 2) precipitation of spar and recrystallization of micrite into spar, 3) replacement of spar and micrite by chert and chalcedony. X-ray powder diffraction analyses confirm the calcite and quartz composition. The sequence is clearly seen within rhizoliths. Micrite root molds outline former roots. Spar filled root casts. The removal of spar through replacement by chert can be identified by the corroded boundaries and scalloped edges of spar root casts.
Rhizoliths, invertebrate bioturbation and breccias indicate pedogenesis of the palustral limestone beds, but carbon (δ13 CPDB from 0 to -2) and oxygen (δ18 OSMOW from 25 to 33) stable isotope analyses of the micrite and spar support precipitation from shallow groundwater of meteoric origin. Since silica replaces spar it is also likely to have a groundwater origin. The temperature of the silica-bearing fluid will be constrained by O-isotope analyses of the silica.
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